Cinnamate free sunscreen. Learn which irritants to avoid.
Cinnamate free sunscreen. Articles of Octyl 4-methoxycinnamate are included as well. Octyl methoxycinnamate is the most widely used UVB blocking… Chemical Sunscreens are versatile and widely-used in many sunscreen formulations Nov 1, 2016 · Many commercial sunscreen lotions use various cinnamate derivatives (figure 2 b) as UV absorbing species. Benzyl cinnamate and cinnamate derivatives. Purity >98%. The ester 1,3-dipalmitoyl-2-p-methoxycinnamoyl-1,2,3propanetriol presented a 2. Cin-CNCs can also serve as This document describes a two-step synthesis of cinnamate ester sunscreen analogs. One of the derivative compounds is known as homosalate. For example, 2-ethylhexyl- E -4-methoxycinnamate (E -EHMC, see structure in Fig. OM-Cinnamate is effective against UVB at the wavelength of 20-330 nm. BALSUM OF PERU CAS No: 8007-00-9. They are suitable for use as UV-shielding nanofillers for sunscreen and transparent polymer films. Recent evidence of high systemic absorption of sunscreen ingredients has raised concerns regarding the safety of sunscreen products. Abstract sunscreen an organic formulations emulsification technique, UV filter, ideal cream bases and titanium with a high sun protection factor (SPF) and desirable properties was the aim of this study. Synonyms: 2- ethylhexyl-p-methoxycinnamate or octinoxate. May 30, 2022 · A chemical sunscreen agent that absorbs UVB and short UVA rays (280-350nm) with its peak protection at 288 nm. It is one of the most tested and widely used UV-B Apr 30, 2015 · Formulation of Sunscreen Cream of Germanicol cinnamate from the Leaves of Tabat barito (Ficus deltoides Jack) and an Assay of its' Sun Protection Factor Among all these UV-B Sunscreen agents octyl methoxy cinnamate accounts for almost 90% of all the Sunscreen agents and has been occupying a pride of place. Octyl Methoxycinnamate is a UV-B category 1 sunscreen used for OTC sun protection products such as sunscreens, personal care products, sun care, baby sun care, daily skin care, decorative cosmetic with sun protection and broad spectrum UV- B filter. g. [2] Studies have evaluated the efficacy of octyl methoxycinnamate in preventing postoperative peritoneal adhesions and determined that octyl methoxycinnamate covering peritoneal surfaces decreases adhesion formation. UV Doux Blue Light Sunscreen Gel SPF 50 PA+++ it is a dermatologically tested gel that can help protect your skin from sun exposure. Unlike many other chemical sunscreens, it is highly stable but its UV absorbing abilities are weak so it always has to be combined with other sunscreen agents for proper protection. See full list on dermnetnz. Octinoxate is a cinnamate ester and common ingredient in sunscreen and other skin care products to minimize DNA photodamage. It has an SPF 50, PA+++ rating and can help reduce the impact of UV rays. It is commonly found in sunscreens and cosmetics to provide sun protection and protect against UV damage. Acnemoist also offers sun protection and contains such ingredients as Jojoba 3%, Octyl Methyl Cinnamate 5%, MBBT 4%, and Pentavitin 1%. Mar 29, 2018 · Slathering on the SPF before hitting the beach? It may be poisoning and destroying the coral reefs “Four commonly found sunscreen ingredients (paraben, cinnamate, benzophenone and a camphor derivative) can awaken dormant viruses in the symbiotic algae called zooxanthellae, which live inside reef In the Laboratory edited by The Microscale Laboratory R. This document discusses cinnamate-functionalized cellulose nanocrystals (Cin-CNCs) that were prepared by esterifying cellulose nanocrystals (CNCs) with cinnamoyl chloride. The possible relaxation pathways were calculated by the (time-dependent) density functional theory. In addition, novel technologies and ultraviolet filters are improving the aesthetics and efficacy of modern products. Flavonoids and cinnamates present in many plant extracts have essential characteristics to be sunscreens, such as absorption of ultraviolet rays, as well as antioxidant activity, usefulness in cosmetics, action against free radicals, and controlling the early ageing caused by various external factors. Acnemoist provides extensive moisturizing for dry skin without making skin look oily. It provides a matte finish and inhibits the formation of radicals and helps in sebum DESCRIPTION: OM-Cinnamate (also known as octinoxate, OMC, etc) is a liquid, oil-soluble organic sunscreen obtained from cinnamon. The first step is the synthesis of trans-4-methoxycinnamic acid via a Verley-Doebner modification of the Knoevenagel condensation of 4-methoxybenzaldehyde and malonic acid. However, concerns have been Ethylhexyl Methoxycinnamate, also known as Octyl Methoxycinnamate or OM-Cinnamate, is an organic compound that serves as a UV filter. org Anyone knows a good chemical sunscreen without cinnamate? There don’t seem to be many AB sunscreens without it. Apr 12, 2019 · Cinnamate-functionalized cellulose nanocrystals (Cin-CNCs) display strong UV absorption and high visible light transmittance, and are suitable for use as UV-shielding nanofillers for sunscreen and transparent polymer films. OMC (Octinoxate, Octyl methoxycinnamate, OM-Cinnamate) Octyl methoxycinnamate or abbreviation OMC or OM-Cinnamate or Octinoxate is an organic sunscreen. The SPF values of the sunscreen cream containing Octyl Methoxycinnamate is a UV-B category 1 sunscreen used for OTC sun protection products such as sunscreens, personal care products, sun care, baby sun care, daily skin care, decorative cosmetic with sun protection and broad spectrum UV- B filter. These are a class of SPF boosters that Specification Sheet Description: Liquid oil soluble UVB sunscreen. In fact, one of the most widely used sunscreen agents, 2-ethylhexyl-4-methoxycinnamate (EHMC, figure 9) [123], falls within this category. They are suitable for use as UV‐shielding nanofillers for sunscreen and transparent polymer films. I haven’t tried them but there’s a new BoJ one (Relief Sun: rice + probiotics SPF50+ PA++++) and also the new Purito (Daily Go-To SPF50+ PA++++). Octinoxate is mainly valued for its ability to absorb UV rays, which produce free radicals, damage healthy skin cells and increase the rate of aging. Jan 29, 2019 · Cinnamate‐functionalized cellulose nanocrystals (Cin‐CNCs) prepared by esterifying CNCs with cinnamoyl chloride display strong UV absorption and high visible light transmittance. overview Ethylhexyl Methoxycinnamate, also known as Octyl Methoxycinnamate or Octinoxate, is a widely used organic, oil-soluble sun filter that absorbs UV-B radiation. The cinnamates are UVB sunscreens and include 2-ethylhexyl-p -methoxy cinnamate (2-EHMC, tradename Parsol MCX) and 2-ethylhexyl-2-cyano-3,3-diphenyl-2-propanoate (2-EHCDP, also known as Octocrylene). Jan 29, 2019 · Cinnamate-functionalized cellulose nanocrystals (Cin-CNCs) prepared by esterifying CNCs with cinnamoyl chloride display strong UV absorption and high visible light transmittance. Oxybenzone (BP-3) and octinoxate (OMC), two common sunscreen ingredients, were recently banned in Key West and Jan 29, 2019 · Cinnamate-functionalized cellulose nanocrystals (Cin-CNCs) prepared by esterifying CNCs with cinnamoyl chloride display strong UV absorption and high visible light transmittance. The aqueous Cin-CNC dispersion is waterborne, alcohol-free, nonwhitening, waterproof, photo-stable, and possesses a high sun protection factor. Oxtinoxate’s texture is like a transparent liquid making it perfectly suitable for “light-weight” sunscreens formula. Oct 12, 2016 · Methyl-E-4-methoxycinnamate (E-MMC) is a model chromophore of the commonly used commercial sunscreen agent, 2-ethylhexyl-E-4-methoxycinnamate (E-EHMC). The nonradiative decay pathways of jet-cooled para-methoxy methylcinnamate (p-MMC) and para-methoxy ethylcinnamate (p-MEC) have been investigated by picosecond pump–probe and nanosecond UV-Deep UV pump–probe spectroscopy. (UVB Wavelength). Can be combined with other sunscreens that protect from UVA rays. Acnemoist® is a specially formulated oil-free moisturizer developed by Curatio Pharmaceuticals. Antioxidants could be, for example, vitamin E or BHT. ( J Am Acad May 17, 2023 · UV filters found in sunscreens first became commercially available in 1928 and were a combination of benzyl salicylate and benzyl cinnamate. Preparation and Evaluation of Sunscreen Nanoemulsions with Synergistic Efficacy on SPF by Combination of Soybean Oil, Avobenzone, and Octyl Methoxycinnamate Conclusions (Cinnamate-zinc layered hydroxide) intercalation compound is suitable to be used as a safe and effective sunscreen with long UV protection effect. Vanicream sensitive skin care products are formulated without common chemical irritants found in ordinary skin care products. 8 times lower hydrolysis rate by lipase, in vitro, than the commercial sunscreen 2-ethylhexyl-p-methoxycinnamate (alkyl ester). The purpose of present task was to evaluate the sun protection factor (SPF) of Germanicol cinnamate in two types of sunscreen formulations FA (W/O) and FB (O/W) by ultraviolet spectroscopic method. We found that p-MMC and p-MEC at low excess energy undergo multistep Active ingredients The active ingredients of sunscreens may be classified as organic or inorganic chemical absorbers. Dicks* Department of Chemistry, University of Toronto, 80 St. The Cin-CNCs display strong UV absorption and high visible light transmittance, making them suitable as UV-shielding nanofillers for sunscreen and transparent polymer films. [2][3] It may be combined with oxybenzone and titanium oxide. However, there are concerns it is harming marine life. The topical application of sunscreens, containing UV-B filters, is widely used to protect against UV-induced damage. Although there are concerns regarding long-term sunscreen safety, the advantages of sunscreen use are far more compelling. By now you probably know the benefits of using a daily sunscreen; octinoxate is a common … Continue reading "Octinoxate – How Safe Is This Sunscreen A cinnamate is a compound closely linked to cinnamon oil and related compounds, frequently utilized as flavorings and fragrances in various toiletries and cosmetics. The second step is the synthesis of ethyl trans-4-methoxycinnamate from trans-4-methoxycinnamic acid using cesium carbonate and iodoethane OM-Cinnamate is incorporated into various sunscreen products, including lotions, creams, sprays, and sticks, to help prevent sunburn and minimize the harmful effects of UV radiation on the skin. The ester 1,3-dipalmitoyl-2-p-methoxycinnamoyl-1,2,3-propanetriol presented a 2. This Jan 29, 2019 · Cinnamate-functionalized cellulose nanocrystals (Cin-CNCs) prepared by esterifying CNCs with cinnamoyl chloride display strong UV absorption and high visible light transmittance. Nov 30, 2022 · Ethylhexyl methoxycinnamate is an ultraviolet (UV) protection agent commonly used in sunscreens, face foundations, and lip care products. UV Doux Sunscreen Spf 50+ Gel is dermatologically tested and clinically proven formula that contains physical UV blockers (zinc oxide, titanium dioxide) and chemical UV blockers (bemotrizinol) and provides a broad spectrum protection against UVA and UVB, thus protects the skin against damage and cancer. Ethyl cinnamate was synthesized from cinnamic acid and ethanol with concentrated sulfuric acid as catalysts Jun 15, 2023 · The purpose of present task was to evaluate the sun protection factor (SPF) of Germanicol cinnamate in two types of sunscreen formulations FA (W/O) and FB (O/W) by ultraviolet spectroscopic method. In the early 1930s, a product containing 10% salol (phenyl salicylate) appeared on the Australian market. ethylhexyl methoxysilicate, isoamyl p-methoxysilicate, octocrylene, and cinoxate) have UV protective properties and are used in cosmetics as sunscreen 27 . Therefore, there is a need for sunscreen or cosmetic compositions of the daily use, which are efficient for sun protection but free of UV filter under discussion. PABA (p-aminobenzoic acid). The guide lists 5 benefits of octinoxate in sunscreen, explains FDA limits, and offers safety insights for healthier skin. OM-Cinnamate, USP is a liquid oil soluble UVB sunscreen. It is often used in combination with other ingredients. Aug 20, 2024 · A Deep Dive into Understanding SPF Boosters and Sunscreen Doping Taking at closer look at chemical SPF boosters butyoctyl salicylate, tridecyl salicylate, polyester-8, ethylhexyl methoxycrylene, and ethyl ferulate We are going to be looking at a specific type of SPF boosters that are becoming much more common in both mineral and ‘chemical’ sunscreens. Unlike other sunscreens that contain harmful chemicals, this gel is completely free from any harsh ingredients, making it safe for use on even the most sensitive skin types. 1 It was not until the 1960s, though, that the nomenclature of sun protection factor (SPF) was developed by Franz Greiter to describe the ability of UV filters to reduce the likelihood of sunburns. The human skin is the first line of photoprotection against harmful exogenous factors, such as UV radiations. This invention relates to an improved process for the manufacture of cinnamate compounds, particularly sunscreen agents, useful in cosmetic skin and hair care formulations. Keywords: Sunscreen, Zinc layered hydroxide, Zinc oxide, Optical properties, Cytotoxicity Background Nov 18, 2019 · When it comes to sunscreen agents, Zinc Oxide is pretty much in a league of its own. Feb 10, 2022 · Octinoxate is a UV filter present in many sunscreens and other cosmetic products. By absorbing these harmful rays, Ethylhexyl Methoxycinnamate helps prevent sunburn and protects the skin Jan 29, 2019 · Request PDF | Cinnamate-Functionalized Cellulose Nanocrystals as UV-Shielding Nanofillers in Sunscreen and Transparent Polymer Films | Sustainable and environmentally friendly UV‐shielding Results presented herein show that the glyceryl esters have similar λ max and ε values to sunscreens of the cinnamate class. If physical sunscreens don't tell you anything, go ahead and read about the basics here. It is a paraben and sulfate-free product that can be mild on your skin. It is an ester formed from methoxycinnamic acid and (RS)-2-ethylhexanol. Dec 24, 2019 · Background Sunlight is one of the main harmful exogenous factors that induce the reactive oxygen species formation. Cinnamates possess high molar absorption coefficients and are heavily used sunscreen ingredients, present in over 90% of sun care products. This is a broad UVB radiation absorbance profile. Stabile and Andrew P. Shea Butter | A Traditional Sun Block I’ve come across some info online that shea butter can’t be used as a sunscreen but did you know that ancient people from Africa have been using pure shea for AGES to protect their skin all around the year? This says a lot, given the intense sunlight, which can be very harsh in many regions especially at the peak of the day (noon). Jul 3, 2019 · Octinoxate (ethylhexyl methoxycinnamate or octyl methoxycinnamate) is a chemical commonly used in sunscreen, it’s one of the oldest sunscreen filters and it’s used to block UVB rays. Aug 21, 2025 · Chemsrc provides Octyl 4-methoxycinnamate (CAS#:5466-77-3) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Learn which irritants to avoid. Their efficacy in reducing photocarcinogenesis and photoaging is widely documented. We provide an overview of sunscreen’s efficacy in sunburn, photocarcinogenesis, photoag-ing, pigmentary disorders, and photodermatoses. Table 3 and Appendix I show those ingredients that are approved for use in Australia, Europe, Japan and the USA. Sunscreen chemical, other names: methyl ester, methyl cinnamate, BENZYL CINNAMATE. Jul 17, 2024 · At the molecular level, Octocrylene is classified as a cinnamate derivative, specifically an ester formed from the condensation of a cinnamic acid derivative and a fatty alcohol known as 2-ethylhexanol. Nextgen SPF50 Sunscreen Gel is a lightweight and non-greasy formula that is easy to apply and absorbs quickly, leaving your skin feeling smooth and moisturized. May 1, 2016 · PDF | An inexpensive, rapid method for the determination of octyl methoxycinnamate (OMC) in sunscreen products using ultraviolet-spectrophotometry has | Find, read and cite all the research you Jan 12, 1995 · This invention relates to an improved process for the manufacture of cinnamate compounds, particularly sunscreen agents, useful in cosmetic skin and hair care formulations. It was originally developed in 1950's as an organic UV-B filter that absorbs UV-B rays from sun. utoronto. samples' physical were created characteristics, viscosity, formulations and in vitro SPF were measured. Octyl methoxycinnamate or abbreviation OMC or OM-Cinnamate or Octinoxate is an organic sunscreen. UV filter under discussion are for example octocrylene, homosalate, ethylhexyl methoxy cinnamate, 4-methylbenzylidene camphor, benzophenone-3 or ethylhexyl salicylate. “Featuring a safe mineral filter—zinc oxide—to shield the skin, it Apr 21, 2025 · Looking for chemical-free sunscreen for healthy & safe skin under the sun? Here are the 10 best non-toxic & natural sunscreen brands! 2 days ago · To find the best non-toxic sunscreens for the face and body with no white cast, we tested 30 chemical-free sunscreens for adults and babies. The Cin-CNC aqueous dispersion has a high sun The cinnamates are UVB sunscreens and include 2-ethylhexyl-p -methoxy cinnamate (2-EHMC, tradename Parsol MCX) and 2-ethylhexyl-2-cyano-3,3-diphenyl-2-propanoate (2-EHCDP, also known as Octocrylene). George Street, Toronto, Ontario, Canada, M5S 3H6; * adicks@chem. Thanks to their significant UVB absorption capabilities, cinnamates find use in sunscreen products and color cosmetics that offer sun protection benefits. It is an effective UVB blocker, but is not waterproof. Jul 26, 2016 · Many of these chromophores are cinnamate-based derivatives which, as well as serving in natural photoprotection, have also found extensive use in artificial photoprotection. Ester of methoxycinnamate made of a derivative of cinnamic acid (occurring in plants like balsam of Peru, cinnamon leaves) with methyl acetate. S. May 2, 2018 · Starting January 2021, the sale of sunscreens containing oxybenzone will be banned throughout the state of Hawaii, making it the first in the U. Octinoxate spectrum range and stability Octinoxate can absorb UVB rays, it’s Feb 4, 2011 · Sunscreens are an important aspect of photoprotection. Mar 29, 2024 · Due to Octyl Methoxycinnamate is a derivative of cinnamate acid (unsaturated fatty acid), an antioxidant should be added to the cosmetic composition, to guarantee the oxidative stability of the product. ca Several laboratory experiments . 1b) is an organic sunscreen filter commonly found in commercial sunscreens. Here the authors propose a symmetric ester This research aimed to determine the yield of ethyl cinnamate synthesized by the sonochemical method and its potency as a sunscreen agent. The risk of developing unwanted allergic contact dermatitis because of cinnamate UV filters in cinnamon-sensitive patients seems to be low, but our study population was small. What Is Octinoxate? Octinoxate is used in sunscreen formulations as a chemical UV absorber. 2 In the 1970s and 1980s, public health campaigns began Dec 1, 1995 · This invention relates to an improved process for the manufacture of cinnamate compounds, particularly sunscreen agents, useful in cosmetic skin and hair care formulations. Ad- and In this article, we review sunscreen active and additive ingredient properties, mechanisms of action and gaps in pro-tection. ingredients at the permitted concentrations. David Crouch Dickinson College Carlisle, PA 17013-2896 Two-Step Semi-Microscale Preparation of a Cinnamate Ester Sunscreen Analog W Ryan G. It is generally considered safe for use in skincare products, with minimal skin irritation. Synopsis An inexpensive, rapid method for the determination of octyl methoxycinnamate (OMC) in sunscreen products using ultraviolet-spectrophotometry has been developed and validated according to Octyl methoxycinnamate is the most common active ingredient in sunscreens for protection against UV-B rays. It's a physical (or inorganic) sunscreen that has a lot in common with fellow inorganic sunscreen Titanium Dioxide (TiO2) but a couple of things make it superior even to TiO2. Of course, your skin Nov 14, 2019 · A cinnamate is a compound chemically related to cinnamon oil and other cinnamon-related compounds that are used widely as flavourings and fragrances in many toiletries and cosmetics. Key Ingredients: Octyl methoxy Cinnamate Diethylaminohydroxyl Zinc Jan 7, 2025 · Octyl Methoxycinnamate Uses, Dosage, Side Effects and more Octyl Methoxycinnamate is a cinnamate ester and common ingredient in sunscreen and other skin care products to minimize DNA photodamage. [0007] Aug 20, 2024 · A Deep Dive into Understanding SPF Boosters and Sunscreen Doping Taking at closer look at chemical SPF boosters butyoctyl salicylate, tridecyl salicylate, polyester-8, ethylhexyl methoxycrylene, and ethyl ferulate We are going to be looking at a specific type of SPF boosters that are becoming much more common in both mineral and ‘chemical’ sunscreens. Octyl Methoxycinnamate in Personal Care Products Discover Octyl Methoxycinnamate's role in skin care, its usage as a UV filter, its impact on product texture, and safety considerations. It is widely used in sunscreen and skincare products due to its ability to absorb ultraviolet B (UVB) radiation, which ranges from 280 to 320 nanometers. Other names: China oil, Indian balsam, Liquid storax, Peru balsam, Perul, Tolu Balsam, also known as 2-ethoxyethyl p-methoxy cinnamate, Cinoxate, Isobutyl salicyl cinnamate, Octinoxate, and Octocrylene. ” Aparovich also praises the ingredients. Jun 5, 2018 · Nevertheless, allergies to sunscreens derived from cinnamic acid are considered uncommon; they are most probably caused by cross-reactivity with similar commonly used perfuming and flavouring ingredients such as cinnamic acid, cinnamaldehyde and certain plant extracts 39, 40. CAS No: 103-41 -3. In an effort to garner a molecular-level understanding of the photoprotection mechanisms in operation with E-EHMC, we have used time-resolved pump-p … Oct 18, 2019 · Sinapate esters are promising nature-inspired sunscreen and antioxidant agents but their photoisomerization may lead to ineffective or harmful species. May 7, 2013 · Ethylhexyl methoxycinnamate (EHMC) is among the most frequently used organic ultraviolet (UV) filters, known primarily for its role as an active ingredient in sunscreen products. Includes Balsam Of Peru and Cinnamates. Cinnamates are also potent UVB absorbers and therefore used in sunscreen agents and colour cosmetics with sun protection factor qualities. an inorganic UV active ingredients. Ethylhexyl Methoxycinnamate is approved worldwide in various concentrations. Jun 25, 2025 · Choosing safe sun care can be tough. May 1, 2025 · “It’s a mineral sunscreen free of harsh chemicals with broad-spectrum coverage. The SPF values of the sunscreen cream containing It is often used in combination with other ingredients. Octylmethoxycinnamate is the world’s most widely Jun 1, 2018 · Ester derivatives of cinnamic acid (e. Feb 26, 2016 · The first reported use of a sunscreen was in the US in 1928, with the commercial introduction of an emulsion containing benzyl salicylate and benzyl cinnamate. Results presented herein show that the glyceryl esters have similar λmax and ɛ values to sunscreens of the cinnamate class. The second step is the synthesis of ethyl trans-4-methoxycinnamate from trans-4-methoxycinnamic acid using cesium carbonate and iodoethane Vanicream sensitive skin care products are formulated without common chemical irritants found in ordinary skin care products. It acts as a UV filter and blocks the Sun’s UV-B rays which have been associated with sunburn and skin cancer, thus protecting the skin. to enact such a law. Besides, octyl methoxy cinnamate (OMC) also known as 2- ethyl-hexyl cinnamate is produced from p-cresol via p- anisic aldehyde and will be discussed here in some detail. Often found in combination with other ingredients. Jun 20, 2012 · Evaluation of octyl p-methoxycinnamate included in liposomes and cyclodextrins in anti-solar preparations: preparations, characterizations and in vitro penetration studies Oct 4, 2024 · But what is the reality? The triterpenic alcohol cinnamate esters, the main component of the unsaponifiable fraction of shea butter, have a strong absorption of UV rays between 250 and 300 nm. Derived from Cinnamic Acid (an acid found in the Cinnamon plant) that is effective in protecting against UVB light. Therefore, we recommend cinnamon-sensitive patients to perform a use test, for example the repeated open application test, b … Results presented herein show that the glyceryl esters have similar λ max and ε values to sunscreens of the cinnamate class. Another early sunscreen agent. It can help prevent skin damage and sunburns. When added to a sunscreen, they synergistically increase the absorption of UVB rays with the sunscreen filters. dlyqmm4zvlhw5iujqxzy4ymulam7wtek6ddny8divqa4